Search results for "fluorinated allylamines"

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Synthesis of fluorinated allylic amines: Reaction of 2-(trimethylsilyl)ethyl sulfones and sulfoxides with fluorinated imines

2007

A new synthesis of fluorinated allylamines through the reaction of 2-(trimethylsilyl)ethyl sulfones and sulfoxides (as vinyl anion equivalents) with imines and imino esters has been described. The process includes a TBAF-mediated fragmentation of 2-(trimethylsilyl)ethyl sulfones to afford the desired allylic amines. When the reaction is performed with the corresponding sulfoxides, the fragmentation takes place under the addition conditions, affording the final products in a single step. (C) 2007 Elsevier B.V. All rights reserved.

Fluorinated iminesAllylic rearrangementTrimethylsilylfluorinated allylaminesChemistryOrganic ChemistrySingle stepBiochemistryInorganic Chemistrychemistry.chemical_compound2-(Trimethylsilyl)ethyl sulfones and sulfoxidesFragmentation (mass spectrometry)Fluorinated imino estersEnvironmental ChemistryOrganic chemistryPhysical and Theoretical ChemistryJournal of Fluorine Chemistry

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